Lacquer



In a general sense, lacquer is a clear or coloured varnish that dries by solvent evaporation and often a curing process as well that produces a hard, durable finish, in any sheen level from ultra matte to high gloss and that can be further polished as required.

The term lacquer originates from the Portuguese word for lac, a type of resin excreted from certain insects. Regardless, in modern usage, lac-based varnishes are referred to as shellac, while lacquer refers to other polymers dissolved in volatile organic compounds (VOCs), such as nitrocellulose, and later acrylic compounds dissolved in lacquer thinner, a mixture of several solvents typically containing butyl acetate and xylene or toluene.

While both lacquer and shellac are traditional finishes, lacquer is more durable than shellac.

Etymology
The French word lacre "a kind of sealing wax", from Portuguese lacre, unexplained variant of lacca "resinous substance", from Arabic lakk, from Persian lak, the verb lac meaning "to cover or coat with laqueur".

Urushiol-based lacquers
According to Encyclopædia Britannica, varnish resin derived from a tree indigenous to China, species Toxicodendron vernicifluum (formerly Rhus vernicifluum), commonly known as the varnish tree. The manufacturing process was introduced into Japan and remained secret for centuries. These lacquers produce very hard, durable finishes that are both beautiful and very resistant to damage by water, acid, alkali or abrasion. The active ingredient of the resin is urushiol, a mixture of various phenols suspended in water, plus a few proteins.



Urushiol-based lacquers differ from most others, being slow-drying, water-based, and set by oxidation and polymerisation, rather than by evaporation alone. In order for it to set properly it requires humidity and warm temperature. The phenols oxidize and polymerize under the action of an enzyme laccase, yielding a substrate that, upon proper evaporation of its water content, is hard. Lacquer skills became very highly developed in India and Asia, and many highly decorated pieces were produced. The process of lacquer application in India is different from China and Japan. There are two types of lacquer: one obtained from the T. Vernicifluum tree and the other from an insect. In India the insect lac was once used from which a red dye was first extracted, later what was left of the insect was a grease that was used for lacquering objects. Insect lac was introduced to India from Persia (Iran). The fresh resin from the T. vernicifluum trees causes urushiol-induced contact dermatitis and great care is required in its use. The Chinese treated the allergic reaction with shell-fish.

The contemporary theory held that from China, knowledge of lacquer technology was introduced to Korea, and from there to Japan. It was believed that Japan had also been using lacquer from ancient times, but the systematic process of application was developed by the Chinese. With the discovery of lacquer ware in Japan dating back to Jōmon period, conflicting theories claim that technology may have been independently developed in Japan. Trade of lacquer objects traveled through various routes to the Middle East. Known applications of lacquer in China included coffins, plates, music instruments and furniture. Lacquer mixed with powdered cinnabar is used to produce the traditional red lacquerware from China.



The trees must be at least 10 years old before cutting to bleed the resin. It sets by a process called "aqua-polymerization", absorbing oxygen to set; placing in a humid environment (called "furo" or "muro" in Japanese, meaning "a bath" or "a room") allows it to absorb more oxygen from the evaporation of the water.

Lacquer-yielding trees in Thailand, Vietnam, Burma and Taiwan, called Thitsi, are slightly different; they do not contain urushiol, but similar substances called "laccol" or "thitsiol". The end result is similar but softer than the Chinese or Japanese lacquer. Unlike Japanese and Chinese Toxicodendron verniciflua resin, Burmese lacquer does not cause allergic reactions; it sets slower, and is painted by craftsmen's hands without using brushes.

Raw lacquer can be "coloured" by the addition of small amounts of iron oxides, giving red or black depending on the oxide. There is some evidence that its use is even older than 8,000 years from archeological digs in China. Later, pigments were added to make colours. It is used not only as a finish, but mixed with ground fired and unfired clays applied to a mould with layers of hemp cloth, it can produce objects without need for another core like wood. The process is called "kanshitsu" in Japan. Advanced decorative techniques using additional materials such as gold and silver powders and flakes ("makie") were refined to very high standards in Japan also after having been introduced from China. In the lacquering of the Chinese musical instrument, the guqin, the lacquer is mixed with deer horn powder (or ceramic powder) to give it more strength so it can stand up to the fingering.



There are more than four forms of urushiol which is written as thus:

R = (CH2)14CH3 or R = (CH2)7CH=CH(CH2)5CH3 or R = (CH2)7CH=CHCH2CH=CH(CH2)2CH3 or R = (CH2)7CH=CHCH2CH=CHCH=CHCH3 or R = (CH2)7CH=CHCH2CH=CHCH2CH=CH2 and others.

Nitrocellulose lacquers
Quick-drying solvent-based lacquers that contain nitrocellulose, a resin obtained from the nitration of cotton and other cellulostic materials, were developed in the early 1920s, and extensively used in the automobile industry for 30 years. Prior to their introduction, mass produced automotive finishes were limited in colour, with Japan Black being the fastest drying and thus most popular. General Motors Oakland automobile brand automobile was the first (1923) to introduce one of the new fast drying nitrocelluous lacquers, a bright blue, produced by DuPont under their Duco tradename.

These lacquers are also used on wooden products, furniture primarily, and on musical instruments and other objects. The nitrocellulose and other resins and plasticizers are dissolved in the solvent, and each coat of lacquer dissolves some of the previous coat. These lacquers were a huge improvement over earlier automobile and furniture finishes, both in ease of application, and in colour retention. The preferred method of applying quick-drying lacquers is by spraying, and the development of nitrocellulose lacquers led to the first extensive use of spray guns. Nitrocellulose lacquers produce a very hard yet flexible, durable finish that can be polished to a high sheen. Drawbacks of these lacquers include the hazardous nature of the solvent, which is flammable, volatile and toxic; and the handling hazards of nitrocellulose in the lacquer manufacturing process. Lacquer grade of soluble nitrocellulose is closely related to the more highly nitrated form which is used to make explosives. They are not toxic after about a month after the lacquer has dissolved all the solvents used to make this kind of lacquer.

Acrylic lacquers
Lacquers using acrylic resin, a synthetic polymer, were developed in the 1950s. Acrylic resin is colourless, transparent thermoplastic, obtained by the polymerization of derivatives of acrylic acid. Acrylic is also used in enamels, which have the advantage of not needing to be buffed to obtain a shine. Enamels, however, are slow drying. The advantage of acrylic lacquer is its exceptionally fast drying time. The use of lacquers in automobile finishes was discontinued when tougher, more durable, weather- and chemical-resistant two-component polyurethane coatings were developed. The system usually consists of a primer, colour coat and clear topcoat, commonly known as clear coat finishes. It is extensively used for wooden finishing.

Water-based lacquers
Due to health risks and environmental considerations involved in the use of solvent-based lacquers, much work has gone in to the development of water-based lacquers. Such lacquers are considerably less toxic and more environmentally friendly, and in many cases, produce acceptable results. More and more water-based colored lacquers are replacing solvent-based clear and colored lacquers in underhood and interior applications in the automobile and other similar industrial applications. Water based lacquers are used extensively in wood furniture finishing as well.

Japanning
Just as "China" is a common name for Chinese ceramic, "Japan" is an old name for Japanese Lacquerware (made from the sap of the Lacquer Tree) and its European imitations. As Asian and Indian lacquer work became popular in England, France, the Netherlands, and Spain in the 17th century the Europeans developed imitations that were effectively a different technique of lacquering. The European technique, which is used on furniture and other objects, uses varnishes that have a resin base similar to shellac. The technique, which became known as japanning, involves applying several coats of varnish which are each heat-dried and polished. In the 18th Century this type of lacquering gained a large popular following. In the 19th and 20th Centuries this lacquering technique evolved into the handicraft of decoupage. The English novelist George Eliot mentions a "lacker box" in her novel Silas Marner.

Korea lacquer use
Other numerous lacquered objects of similar time scale have been found in Korea. There is growing evidence that various lacquered objects were made and sold throughout the region.